Watching chemistry happen – dynamic studies of light-induced transformations in linkage isomerism complexes
نویسندگان
چکیده
منابع مشابه
Light-induced metastable linkage isomers of ruthenium sulfur dioxide complexes.
The irradiation of ruthenium-sulfur dioxide complexes of general formula trans-[Ru(II)(NH(3))(4)(SO(2))X]Y with laser light at low temperature results in linkage isomerization of SO(2), starting with eta(1)-planar S-bound to eta(2)-side S,O-bound SO(2). The solid-state photoreaction proceeds with retention of sample crystallinity. Following work on trans-[Ru(NH(3))(4)Cl(eta(1)-SO(2))]Cl and tra...
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The reaction of cis,fac-[RuCl2(dmso-S)3(dmso-O)], 1, with different azole (L) ligands leads to new [RuCl2(L)(dmso-S)3] compounds (L = CH3-pz-H, 2; NO2-pz-H, 3; CF3-pz-H, 4 and Br-Hind, 5). Complexes 2-5 have been characterized by analytical, spectroscopic and electrochemical techniques as well as by monocrystal X-ray diffraction analysis. Upon oxidation to Ru(iii) the complexes undergo linkage ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances
سال: 2018
ISSN: 2053-2733
DOI: 10.1107/s2053273318093415