Vibrational analysis of methyl cation—Rare gas atom complexes: CH3+—Rg (Rg = He, Ne, Ar, Kr)
نویسندگان
چکیده
منابع مشابه
Electronic spectroscopy of the R·SH (R=Ne, Ar, Kr) complexes
The laser induced fluorescence spectra of the thiohydroxyl radical inert gas complexes, R·SH (R=Ne, Ar, and Kr) are reported. The spectra of numerous isotopomers involving 32S, 34S, 84Kr, 86Kr, 1H, and 2H have been observed. By using isotopic shifts of the heavy atoms, and other observations, the overwhelming majority of the 60 observed vibronic transitions have been assigned as originating fro...
متن کاملTheoretical study of Cl(-)RG (rare gas) complexes and transport of Cl- through RG (RG = He-Rn).
We present a systematic investigation of the accuracy of the various theories and basis sets that can be applied to study the interaction of Cl(-) ions with Ar atoms. It is conclusively shown that gaseous ion mobility can distinguish among theoretical ion-neutral interaction potentials. Based on the conclusions, high-level ab initio potential energy curves are obtained for all of the Cl(-)-RG (...
متن کاملTHE EXTENDED LAW OF CORRESPONDING - STATES AND THE INTERMOLECULAR POTENTIALS FOR Ar-Ar, Ar-Kr AND Kr-Kr
An inversion procedure is used to obtain from the extended principle of corresponding - states the pair interaction potentials for argon, krypton and its mixture over a tetnperature range from absolute zero to the onset of ionization. The experimentally-reduced viscosity collision integrals obtained from the corresponding - states correlation have been inverted directly to give the reduced...
متن کاملHigh resolution electronic spectroscopy of the R · SH complexes ( R = Ne , Ar , Kr )
The high resolution laser induced fluorescence spectra of the à 2Σ+−X̃ Π3/2 electronic transition of the R·SH/D (R= Kr, Ar, Ne) van der Waals (vdW) complexes are reported. Analysis of these bands requires the inclusion of rotation, fine and hyperfine structure, spin-rotation interactions, and parity splittings. A number of molecular parameters are determined, along with internuclear bond distanc...
متن کاملthe extended law of corresponding - states and the intermolecular potentials for ar-ar, ar-kr and kr-kr
an inversion procedure is used to obtain from the extended principle of corresponding - states the pair interaction potentials for argon, krypton and its mixture over a tetnperature range from absolute zero to the onset of ionization. the experimentally-reduced viscosity collision integrals obtained from the corresponding - states correlation have been inverted directly to give the reduced-inte...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2019
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.5084100