Vertically Resolved Magma Ocean–Protoatmosphere Evolution: H 2 , H 2 O, CO 2 , CH 4 , CO, O 2 , and N 2 as Primary Absorbers

O + + H 2 O „ + M ... \ H 5 O 2 + „ + M ...

Collisional dissociation cross sections for O + O 2 , CO andN 2 , O 2 + O 2 , N + N 2 , andN 2 + N 2

Using laboratory data for the scattering of O by O2, CO and N2 pair potentials are constructed for O, C and N atoms. These potentials are then used to calculate collisional dissociation and energy transfer cross sections for O on O2, CO and N2; O2 on O2, N on N2, and N2 on N2. Since the energetic ions often neutralize in the atmosphere corona, such cross sections are relevant to plasma ion bomb...

Kinetics of HO 2 + HO 2 ! H 2 O 2 + O 2 : Implications for Stratospheric H

[1] The reaction HO2 + HO2 ! H2O2 + O2 (1) has been studied at 100 Torr and 222 K to 295 K. Experiments employing photolysis of Cl2/CH3OH/O2/N2 and F2/H2/O2/N2 gas mixtures to produce HO2 confirmed that methanol enhanced the observed reaction rate. At 100 Torr, zero methanol, k1 = (8.8 ± 0.9) 10 13 exp[(210 ± 26)/T] cm molecule 1 s 1 (2s uncertainties), which agrees with current recommendations...

Cu(2)[o-Br-C(6)H(3)(CO(2))(2)](2)(H(2)O)(2).(DMF)(8)(H(2)O)(2): a framework deliberately designed to have the NbO structure type.

The synthesis of an NbO-type metal-organic framework was achieved by design: o-Br-BDC (BDC = benzenedicarboxylate) was used to direct the formation of Cu2(CO2)4 paddle wheel units at 90 degrees to each other and thus yield the target network. The compound was formulated as Cu2[o-Br-BDC]2(H2O)2.(DMF)8(H2O)2 (MOF-101) and characterized by single-crystal X-ray diffraction [cubic, space group Imm (...

1 CO 2 - Retention Capapility of CH 4 / O 2 - Fired Graz Cycle

The Graz Cycle, a hydrogen oxygen fired double loop high temperature steam cycle, combining gas turbine philosophy with steam plant praxis, can be adapted for combustion of methane with oxygen. The resulting combustion products carbon dioxide and hydrogen oxide, i.e. high temperature steam, are mixed with cooling steam and expanded to lowest pressure and temperature. By condensing the steam, se...