Vapor‐Phase Charge—Transfer Complexes. Diethyl Sulfide—Iodine
نویسندگان
چکیده
منابع مشابه
Restoration of Conductivity with TTFTCNQ ChargeTransfer Salts
The formation of the conductive TTF-TCNQ (tetrathiafulvalene– tetracyanoquinodimethane) charge-transfer salt via rupture of microencapsulated solutions of its individual components is reported. Solutions of TTF and TCNQ in various solvents are separately incorporated into poly(urea-formaldehyde) core–shell microcapsules. Rupture of a mixture of TTF-containing microcapsules and TCNQ-containing m...
متن کاملPreparation and Properties of Macrocyclic Ligand and Its Complexes Derived from Trimethoprim and Diethyl Phthalate
Macrocyclic complexes of Mn, Co, Ni and Cu using a macrocyclic ligand derived by the condensation of Trimethoprim and diethyl phthalate have been prepared and characterized by electronic, IR and NMR spectral studies as well as magnetic moment and conductivity. On the basis of spectral studies, an octahedral geometry has been proposed for all the complexes. INTRODUCTION: The chemistry of macrocy...
متن کاملHyperconjugation in diethyl ether cation versus diethyl sulfide cation.
Ionization of a molecule can greatly alter its electronic structure as well as its geometric structure. In this collaborative experimental and theoretical study, we examined variance in hyperconjugation upon ionization of diethyl ether (DEE) and diethyl sulfide (DES). We obtained the experimental gas phase vibrational spectra of DEE, DES, DEE(+), DES(+), DEE(+)-Ar, and DES(+)-Ar in the wavenumb...
متن کاملDiethyl pyrazine-2,5-dicarboxylate
The mol-ecule of the title compound, C(10)H(12)N(2)O(4), is located around an inversion center. The carboxyl-ate groups are twisted slightly with respect to the pyrazine ring, making a dihedral angle of 2.76 (19)°. In the crystal, mol-ecules are stacked along the c axis via weak C-H⋯O hydrogen bonds.
متن کامل1,3-Diethyl-1,3-diphenylurea
The mol-ecule of the title compound, C(17)H(20)N(2)O, a symmetrical derivative of urea, shows non-crystallographic C(2) symmetry. Inter-action with the aromatic system of the phenyl substituents as well as amide-type resonance is responsible for the marked planarization of the coordination environments of the N atoms. C-H⋯O contacts give rise to the formation of centrosymmetric dimers in the cr...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1965
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.1726402