Unique stiffness-deformability features of dendrimeric silica reinforced HDPE nanocomposites obtained by an innovative route

نویسندگان

چکیده

A set of dendrimeric silica (DS) reinforced polyethylene-based nanocomposites is prepared using a novel and straightforward in-situ catalyst supporting procedure by means “in-situ” polymerization technique, labeled DS-SA. These materials are characterized with regard to molar masses, filler dispersion, thermal stability, crystalline characteristics, properties mechanical response then compared an equivalent samples more common method, named DS-MAO, as well non-reinforced HDPE reference. The performance all these discussed based on the features masses polymeric component together dispersion DS nanofiller. results this study confirm potential DS-SA approach innovative promising resulting achieving superior significantly higher their DS-MAO analogues at high loadings, while retaining limit stretching ability HDPE.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Properties of Hdpe/clay/wood Nanocomposites

Composites based on high density polyethylene (HDPE), pine flour, and organic clay were made by melt compounding and then injection molding. The influence of clay on crystallization behavior, mechanical properties, water absorption, and thermal stability of HDPE/pine composites were investigated. The HDPE/pine composites containing exfoliated clay were made by a two-step melt compounding proced...

متن کامل

CHARACTERIZATION OF HIGH-SILICA MORDENITE OBTAINED BY DIRECT SYNTHESIS

Three high-silica mordenite zeolites differing in SiO440, ratio were prepared by direct synthesis without using any template. The products Si02/A120, ratio is influenced by the starting gel composition. This ratio is increased upon ion-exchange with NH,Cl and subsequent calcination to prepare protonic mordenite. The protonic mordenites with Si02/A1203ra tios of 14.6,29.2 and 34.6 were chara...

متن کامل

Thermo-mechanical properties of polymer nanocomposites reinforced with randomly distributed silica nanoparticles- Micromechanical analysis

A three-dimensional micromechanics-based analytical model is developed to study thermo-mechanical properties of polymer composites reinforced with randomly distributed silica nanoparticles. Two important factors in nanocomposites modeling using micromechanical models are nanoparticle arrangement in matrix and interphase effects. In order to study these cases, representative volume element (RVE)...

متن کامل

Bond Deformability of Reinforced Concrete Members

The usual earthquake resistant design philosophy of ductile frame buildings allows the beams to form plastic hinges adjacent to beam-column connections. In order to carry out this design philosophy, the ultimate bond or shear strength of the beam should be greater than the flexural yielding force and should not degrade before reaching its required ductility. The behavior of RC members dominated...

متن کامل

Mesoporous silica reinforced by silica nanoparticles to enhance mechanical performance.

Silica nanoparticle/mesoporous silica composite films were prepared by direct mixing with mechanical stirring and thermal imidization. The structural morphology was elucidated by scanning electron microscopy and the surface of the film was imaged by atomic force microscopy. The functional groups and desorption process of the films were elucidated by Fourier transform infrared spectroscopy and t...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Microporous and Mesoporous Materials

سال: 2022

ISSN: ['1873-3093', '1387-1811']

DOI: https://doi.org/10.1016/j.micromeso.2021.111619