Unique reactivity characteristics of Mo-coordinated S2−2 and S2−4 ligands
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چکیده
منابع مشابه
Unique Reactivity Characteristics of Mo-coordinated !&- and S$- Ligands
The synthesis of the new dithiolene complexes, [{(MeOOC),C,S2}2Mo(2-S)]; and [OMo(S2C2(COOMe)2)2]2, is reported. These complexes are obtained by the reaction of dicarbomethoxyacetylene (DMA) with either [(S~)MO(S)(~~-S)~MO(S)(S~)]~or [(CS~)MO(S)(~~-S)~MO(S)(CS~)]~and [OMO(S~)~]~-, respectively. The reaction of [(S4)Mo(0)(~2-S)2Mo(O)(S2)]2with DMA results in the new dithiolene complex [{(MeOOC)2...
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ژورنال
عنوان ژورنال: Polyhedron
سال: 1986
ISSN: 0277-5387
DOI: 10.1016/s0277-5387(00)84932-3