Unimolecular Solvolyses in Ionic Liquid: Alcohol Dual Solvent Systems
نویسندگان
چکیده
منابع مشابه
Unimolecular Solvolyses in Ionic Liquid: Alcohol Dual Solvent Systems.
A study was undertaken of the solvolysis of pivaloyl triflate in a variety of ionic liquid:alcohol solvent mixtures. The solvolysis is a kΔ process (i.e., a process in which ionization occurs with rearrangement), and the resulting rearranged carbocation intermediate reacts with the alcohol cosolvent via two competing pathways: nucleophilic attack or elimination of a proton. Five different ionic...
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ژورنال
عنوان ژورنال: Molecules
سال: 2016
ISSN: 1420-3049
DOI: 10.3390/molecules21010060