Ultrashort Mn–Mn Bonds in Organometallic Complexes
نویسندگان
چکیده
منابع مشابه
METAL-LIGAND MULTIPLE BONDS IN ORGANOMETALLIC COMPLEXES CONTAINING TRIAMIDOAMINE LIGAND SYSTEMS by JOEL
Chapter 1 The synthesis and reactivity of [N3N]Ta=E complexes is presented where E is a la, l or la, 21t donor and [N3N] 3= [(Me3SiNCH 2CH2)3N]. [N3N]Ta=PPh reacts with excess lithium metal in tetrahydrofuran to give "[N3N]Ta=PLi" which reacts with RX at -35 'C to afford the phosphinidene complexes, [N3N]Ta=PR (R = Me, n-Bu, SiMe3 , SiMe2Ph). [N3N]TaCl 2 reacts with two equivalents of LiN(H)R (...
متن کاملCatalytic organometallic anticancer complexes.
Organometallic complexes offer chemistry that is not accessible to purely organic molecules and, hence, potentially new mechanisms of drug action. We show here that the presence of both an iodido ligand and a sigma-donor/pi-acceptor phenylazopyridine ligand confers remarkable inertness toward ligand substitution on the half-sandwich "piano-stool" ruthenium arene complexes [(eta(6)-arene)Ru(azpy...
متن کاملOrganometallic complexes as anion hosts.
New anion hosts have been accessed using cationic organometallic fragments with sufficient kinetic stability as geometry-organizing cores, simple ditopic ligands featuring hydrogen bond donor groups, and the inert, low interacting, lipophilic BAr'(4) anion.
متن کاملCyclopropenation of organometallic vinylidene complexes
The chemistry of metal cyclopropenyl complexes derived from deprotonation of cationic ruthenium vinylidene complexes is reviewed. Such a metal coordinated cyclopropenyl ligand can be used for the preparation of heterocyclic compounds. The chemical reactivity of cyclopropenyl complexes is influenced by the nature of substituents on the three-membered ring and by the nature of ancillary ligand ar...
متن کاملThe Nature of Halogen Bonds in [N∙∙∙X∙∙∙N]+ Complexes: A Theoretical Study
The effects of substituents on the symmetry and the nature of halogen bonds in [N∙∙∙X∙∙∙N]+-type systems are presented for the YC5H4N∙∙∙X∙∙∙NC5H5 (Y = NO2, CN, H, CH3, OCH3, OH, NH2, X = Cl, Br, I) complexes. Some structural parameters, energy data and electronic properties were explored with...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Physical Chemistry C
سال: 2017
ISSN: 1932-7447,1932-7455
DOI: 10.1021/acs.jpcc.7b07828