Tuning the Hydrophobicity of Zinc Dipyridyl Paddlewheel Metal–Organic Frameworks for Selective Sorption
نویسندگان
چکیده
منابع مشابه
Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks.
Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H(2)bdc) and 2-halo-1,4-benzenedicarboxylic acid (H(2)bdc-X, X = Br or I) to give [Zn(4)O(bdc)(3-x)(bdc-X)(x)], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.
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ژورنال
عنوان ژورنال: Crystal Growth & Design
سال: 2013
ISSN: 1528-7483,1528-7505
DOI: 10.1021/cg400342m