Triarylborane catalysed N-alkylation of amines with aryl esters
نویسندگان
چکیده
منابع مشابه
Reductive hydroxyalkylation/alkylation of amines with lactones/esters.
We have developed a one-pot method for the direct intermolecular reductive hydroxyalkylation or alkylation of amines using lactones or esters as the hydroxyalkylating/alkylating reagents. The method is based on the in situ amidation of lactones/esters with DIBAL-H-amine complex (for primary amines) or DIBAL-H-amine hydrochloride salt complex (for secondary amines), followed by reduction of the ...
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Borrowing hydrogen (or hydrogen autotransfer) reactions represent straightforward and sustainable C-N bond-forming processes. In general, precious metal-based catalysts are employed for this effective transformation. In recent years, the use of earth abundant and cheap non-noble metal catalysts for this process attracted considerable attention in the scientific community. Here we show that the ...
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1. A new method for synthesizing aryl esters of N-acylamino acids is described. The unsymmetrical anhydride resulting from the interaction of an N-acylamino acid and diphenylketen is allowed to react with a phenol. Cleavage of the anhydride by the phenol usually occurs in the desired direction. 2. Bacitracin has been examined as an enzyme model by determining its catalytic activity towards the ...
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An iron oxide immobilized palladium catalyst was prepared for the N-alkylation of amines with alcohols under base and organic ligand free conditions. Applying the optimized reaction conditions, the coupling reactions of amines and alcohols with various structures could be realized with up to 99% isolated yields. The catalysts were studied by XRD, BET, and XPS and the mechanism was studied by DF...
متن کاملN-heterocyclic carbene catalysed aerobic oxidation of aromatic aldehydes to aryl esters using boronic acids.
The organocatalytic behavior of N-heterocyclic carbenes in the aerobic oxidation of aromatic aldehydes to esters with boronic acids has been explored. This transition metal-free protocol allows access to a wide variety of aromatic esters in good to excellent yields under mild reaction conditions.
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ژورنال
عنوان ژورنال: Catalysis Science & Technology
سال: 2020
ISSN: 2044-4753,2044-4761
DOI: 10.1039/d0cy01339k