Trace Determination of Palladium in Environmental Samples by Adsorptive Voltammetry
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چکیده
منابع مشابه
Determination of trace amounts of lead by adsorptive cathodic stripping voltammetry in the presence of xylenol orange
Lead forms the complexes with xylenol orange in the basic solution. An adsorptivedifferential pulse stripping method for the determination of lead is proposed. The procedureinvolves an adsorptive accumulation of lead on a hanging mercury drop electrode (HMDE) inthe presence of xylenol orange, followed by reduction of adsorbed lead by voltammetric scanusing differential pulse modulation. The opt...
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The present work describes a selective, rapid and sensitive method for the determination of cobalt using the adsorptive differential pulse voltammetry technique. The method is based on the accumulation of Co(II) complex with 2-aminocyclopentene-1-dithiocarboxylic acid on a hanging mercury drop electrode, followed by measurement of the current of the adsorbed complex. The effects of experimental...
متن کاملDetermination of trace amounts of thallium by adsorptive cathodic stripping voltammetry with xylenol orange.
Trace amounts of thallium(I) can be determined using adsorptive cathodic stripping voltammetry in the presence of Xylenol Orange (XO). The reduction current of the thallium(I)-XO complex ion was measured by square-wave cathodic stripping voltammetry. The peak potential was at -0.44 V vs. Ag/AgCl. The effect of various parameters (pH, ligand concentration, accumulation potential and collection t...
متن کاملSimultaneous Determination of Trace Amounts of Lead and Zinc by Adsorptive Cathodic Stripping Voltammetry
A selective and sensitive method for simultaneous determination of lead and zinc by adsorptive differential pulse cathodic stripping voltammetry is presented. The method is based on adsorptive accumulation of the complexes of Pb (II) and Zn(II) ions with Dopamine onto hanging mercury drop electrode (HMDE), followed by reduction of adsorbed species by differential pulse cathodic stripping voltam...
متن کاملElectrochemical Determination of Pindone in Agricultural Formulation and Cereal Samples by Differential Pulse Adsorptive Stripping Voltammetry
A sensitive method for the determination of the herbicide pindone by adsorptive stripping voltammetry using a hanging mercury drop electrode at pH 4.0 was described. The cyclic voltammogram of pindone demonstrates that compound was adsorbed at the surface of mercury electrode, and the overall reduction process was under controlled diffusion. The adsorptive peak was observed at −0.3 V, and peak ...
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ژورنال
عنوان ژورنال: Portugaliae Electrochimica Acta
سال: 2005
ISSN: 1647-1571
DOI: 10.4152/pea.200502333