Three Cyanide-Bridged One-Dimensional Single Chain CoIII-MnIIComplexes: Rational Design, Synthesis, Crystal Structures and Magnetic Properties

The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties.

Two cyanide-bridged enantiopure one-dimensional single chain complexes, [Mn((R,R)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (1) and [Mn((S,S)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (2), have been synthesized and structurally characterized. Systematically magnetic investigations show the antiferromagnetic coupling between the cyanide-bridged Mn(III)-Fe(III) centers and the interesting metamagnetic behavior at about ...

Two-dimensional cyanide-bridged heterobimetallic complexes based on CpCoðCNÞ3 : Syntheses, structures and magnetic properties

Using the half-sandwich tricyanometalate, KCpCo(CN)3 (1, Cp = cyclopentadienyl), as the building block, two new cyano-bridged heterobimetallic complexes, [{CpCo(CN)3}2M(H2O)2] Æ 2H2O (M = Fe , 2; Co, 3), have been synthesized and structurally characterized. Complexes 2 and 3 are isostructural. In each complex, [CpCo(CN)3] acts as a bis-monodentate bridging ligand toward the central [M(H2O)2] 2+...

New copper(II)-radical one dimensional chain: Synthesis, crystal structure, EPR, magnetic properties and DFT calculations.

The novel chain compound [Cu(Phtfac)(2)(NITpPy)](n) (where NITpPy = 4-pyridyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide and Phtfac = 4,4,4-trifluoro-1-phenylbutane-1,3-dione) was synthesized and characterized structurally, magnetically and by EPR. The compound contains two non equivalent Cu(II) ions, Cu1 and Cu2, located at inversion centers and bridged by a NITpPy ligand coordinating Cu1 t...

Transmission properties of one dimensional fractal structures

In this paper, the optical properties of one dimensional fractal structures are investigated. We consider six typical fractal photonic structures: the symmetric dual cantor-like fractal structure, the asymmetric dual cantor-like fractal structure, the single cantor-like fractal structure, the symmetric dual golden-section fractal structure, the asymmetric dual golden-section fractal structure a...

Magnetic and crystal structures of the one-dimensional ferromagnetic chain pyroxene NaCrGe2O6