منابع مشابه
Thermodynamics of supercooled water.
We review the available experimental information on the thermodynamic properties of supercooled water and demonstrate the possibility of modeling these thermodynamic properties on a theoretical basis. We show that by assuming the existence of a liquid-liquid critical point in supercooled water, the theory of critical phenomena can give an accurate account of the experimental thermodynamic-prope...
متن کاملSingularity-free interpretation of the thermodynamics of supercooled water.
Srikanth Sastry,* Pablo G. Debenedetti, Francesco Sciortino, and H. E. Stanley Physical Sciences Laboratory, Division of Computer Research and Technology, National Institutes of Health, Bethesda, Maryland 20952 Department of Chemical Engineering, Princeton University, Princeton, New Jersey 08544 Dipartimento di Fisica, Universitá di Roma La Sapienza and Istituto Nazionale per la Fisica della Ma...
متن کاملTwo-state thermodynamics of the ST2 model for supercooled water.
Thermodynamic properties of the ST2 model for supercooled liquid water exhibit anomalies similar to those observed in real water. A possible explanation of these anomalies is the existence of a metastable, liquid-liquid transition terminated by a critical point. This phenomenon, whose possible existence in real water is the subject of much current experimental work, has been unambiguously demon...
متن کاملSingularity-free interpretation of the thermodynamics of supercooled water. II. Thermal and volumetric behavior
According to the singularity-free interpretation of the thermodynamics of supercooled water, the isothermal compressibility, isobaric heat capacity, and the magnitude of the thermal expansion coefficient increase sharply upon supercooling, but remain finite. No phase transition or critical point occurs at low temperatures. Instead, there is a pronounced but continuous increase in volume and a c...
متن کاملRecent results on the connection between thermodynamics and dynamics in supercooled water.
We review recent results on the connection between thermodynamics and dynamics in a model for water. We verify the Adam-Gibbs relation between entropy and dynamic properties using computer simulations, which allow direct access to the relevant properties. We combine experimental measurements of entropy with the Adam-Gibbs hypothesis to predict dynamic properties in deeply supercooled states, wh...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2012
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.3690497