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"Four-potential" ferrocene labeling of PNA oligomers via click chemistry.
The scope of the Cu(I)-catalyzed [2 + 3] azide/alkyne cycloaddition (CuAAC, click chemistry) as a key reaction for the conjugation of ferrocene derivatives to N-terminal functionalized PNA oligomers is explored herein (PNA: peptide nucleic acid). The facile solid-phase synthesis of N-terminal azide or alkyne-functionalized PNA oligomer precursors and their cycloaddition with azidoferrocene, eth...
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2016
ISSN: 1434-1948
DOI: 10.1002/ejic.201601409