The Chemistry of Silicon-Containing Ladder .PI.-Conjugated Systems
نویسندگان
چکیده
منابع مشابه
Diboron-containing fluorophores with extended ladder-type π-conjugated skeletons.
A series of ladder type π-conjugated diboron complexes 1-4 have been designed and synthesized by a very simple synthetic procedure. Single crystals of complex 3 were grown and the molecular structure determined by X-ray diffraction analysis demonstrated that this type of diboron ladder has a rather planar skeleton. All complexes possess very high melting points (275-383 °C) and decomposition te...
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Fully conjugated ladder polymers (cLPs), in which all the backbone units on the polymer main-chain are π-conjugated and fused, have attracted great interest owing to their intriguing properties, remarkable chemical and thermal stability, and potential suitability as functional organic materials. The synthesis of cLPs can be, in general, achieved by two main strategies: single-step ladderization...
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The redox properties of metalloporphyrins have been studied extensively, and particular attention has been paid to the changes in oxidation states of the metaL t-3 In general, the most stable metalloporphyrins are those in which the metal is in the + 2 oxidation state. However, most of the transition metalloporphyrins show a variety of oxidation states. Thus Co(ll) porphyrins can, like the corr...
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Using pulse radiolysis and triplet energy transfer has enabled us to measure the triplet energies in a broad range of different pi-conjugated polymers. In all cases we find that the 1 (3)B(u) is of order 0.6 to 1 eV below the 1 (1)B(u), indicative of localized triplet states with strong electron-electron correlation. We also observe that the 1 (1)A(g)-1 (3)B(u) gap decreases linearly as the 1 (...
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Aniong the known classes of nonlinear optical materials, z-conjugated polymers are very attractive because of their large, third-order optical susceptibilities and ultrafast response times.lP5 The large optical nonlinearity of conjugated polymers has long been recognized as arising from the z-electron delocalization along the polynler chains2 Recently, aromatic heterocyclic ladder-type polymers...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 2005
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.63.1115