Tetrakis(1-ethyl-1H-imidazole-κN3)bis(thiocyanato-κN)cadmium(II)
نویسندگان
چکیده
منابع مشابه
2-Ethyl-1H-imidazole-4-carboxylate monohydrate
In the title compound, C(7)H(8)N(2)O(4)·H(2)O, the imidazole N atom is protonated and one of the carboxyl-ate groups is deprontonated, forming a zwitterion. The two carboxyl groups are are approximately coplanar with the imidazole ring [O-C-C-C torsion angles = -176.8 (2) and 2.9 (4)° for one group and -4.6 (3) and 176.4 (2)° for the other] and have an intra-molecular O-H⋯O hydrogen bond betwee...
متن کاملBromidotetrakis(2-ethyl-1H-imidazole-κN 3)copper(II) bromide
The Cu(II) ion in the title mol-ecular salt, [CuBr(C5H8N2)4]Br, is coordinated in a square-pyramidal geometry by four N atoms of imidazole ligands and one bromide anion in the apical position. In the crystal, the ions are linked by N-H⋯Br hydrogen bonds involving both the coordinating and the free bromide species as acceptors. A C-H⋯Br inter-action is also observed. Overall, a three-dimensional...
متن کاملSynthesis and Structure of 1-Ethyl-2,4,5-triphenyl-1H-imidazole (Ethyl-Lophine)
Ethyl-Lophine, 1-ethyl-2,4,5-triphenyl-1H-imidazole, C23H20N2, was synthesized as a precursor for large organic cations in ionic liquids using an improved microwave-assisted method. The title compound and a precursor compound were characterized by NMR, IR, and DSC thermal measurements, as well as elemental analyses. The crystal structure of ethyl-lophine was determined by singlecrystal X-ray st...
متن کاملcatena-Poly[[bis(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[bis(1-ethyl-1H-imidazole-κN 3)cadmium]]
The asymmetric unit of the crystal structure of the title compound, [Cd(2)Cl(4)(C(5)H(8)N(2))(3)](n), contains two Cd(II) cations, three 1-ethyl-1H-imidazole ligands, and four Cl(-) anions. The two Cd(II) atoms have quite different coordination environments: one is octa-hedrally coordinated by four Cl atoms and two N atoms from two 1-ethyl-1H-imidazole ligands, and the second is in a severely d...
متن کامل1-Ferrocenylmethyl-1H-imidazole
In the title compound, [Fe(C(5)H(5))(C(9)H(9)N(2))], the distances of the Fe atom from the centroids of the unsubstituted and the substituted cyclo-penta-dienyl (cp) rings are 1.639 (1) and 1.647 (1) Å, respectively. The ferrocenyl unit deviates from an eclipsed geometry with tilted cp rings; the inter-planar angle between the cp and imidazole rings is 114.11 (4)°.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810004964