Temperature‐dependent rate constants for the reactions of chlorine atom with methanol and Br2
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چکیده
منابع مشابه
Rate Constants for Reactions between Iodine- and Chlorine-Containing Species: A Detailed Mechanism of the Chlorine Dioxide/Chlorite-Iodide Reaction†
The chlorite-iodide reaction is unusual because it is substrate-inhibited and autocatalytic. Because analytically pure ClO2 ion is not easily prepared, it was generated in situ from the rapid reaction between ClO2 and I-. The resulting overall reaction is multiphasic, consisting of four separable parts. Sequentially, beginning with mixing, these parts are the (a) chlorine dioxide-iodide, (b) ch...
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15 صفحه اولEvaluation of basis sets and theoretical methods for estimating rate constants of mercury oxidation reactions involving chlorine
The occurrence of elemental mercury in flue gases from coal combustion is a problem of current environmental concern. Oxidized mercury species can be effectively removed from the flue gases by chemical scrubbers. However, the detailed mechanism by which oxidation occurs remains unclear. Theoretical rate constants are calculated for mercury oxidation by atomic chlorine. The potential energy surf...
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ژورنال
عنوان ژورنال: International Journal of Chemical Kinetics
سال: 2020
ISSN: 0538-8066,1097-4601
DOI: 10.1002/kin.21351