Synthesis, Structure, and Acidity Constants of Ligated α‐Boryl Acetic Acids
نویسندگان
چکیده
منابع مشابه
Chemical properties of bile acids. IV. Acidity constants of glycine-conjugated bile acids.
The dissociation constants for the carboxyl group of a series of glycine (N-acyl)-conjugated and unconjugated bile acids were determined by potentiometric titration using dimethylsulfoxide-water and methanol-water mixtures of varying proportions. The pKa values in water were calculated by extrapolating the experimental values determined in different mole fractions of the organic solvent mixture...
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15 صفحه اولSimple synthesis of 2-C-branched glyco-acetic acids.
Only three steps are required for the selective synthesis of 2-C-branched glyco-acetic acids from glycals by radical addition and decarboxylation.
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2017
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.201705754