Synthesis of poly(ethyl acrylate) by single electron transfer-degenerative chain transfer living radical polymerization in water catalyzed by Na2 S2 O4
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چکیده
منابع مشابه
Modeling of Reversible Chain Transfer Catalyzed Polymerization by Moment Equations Method
A moment equations method was performed to study the Reversible chain Transfer Catalyzed Polymerization (RTCP) of styrene in 80°C. To do this, a kinetic scheme containing conventional free radical polymerization reactions and equilibrium reactions of RTCP was assumed. After obtaining mass balance equations, three moment equations were defined for free and dormant radicals and dead chains. M...
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15 صفحه اولpoly(styrene-co-butyl acrylate)/clay nanocomposite latexes synthesized via in situ atom transfer radical polymerization in miniemulsion: activators generated by electron transfer approach
w ater born poly(styrene-butyl acrylate)/clay nanocomposite latexes were synthesized by a novel initiating system of activators generated by electron transfer (aget) in a system of atom transfer radical polymerization (atrp). initially, the clay was swelled in a mixture of styrene, butyl acrylate, and hexadecane. the mixture was then sonicated to obtain a stable miniemulsion. to s...
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This Perspective presents recent advances in macromolecular engineering enabled by ATRP. They include the fundamental mechanistic and synthetic features of ATRP with emphasis on various catalytic/initiation systems that use parts-per-million concentrations of Cu catalysts and can be run in environmentally friendly media, e.g., water. The roles of the major components of ATRP--monomers, initiato...
متن کاملmodeling of reversible chain transfer catalyzed polymerization by moment equations method
a moment equations method was performed to study the reversible chain transfer catalyzed polymerization (rtcp) of styrene in 80°c. to do this, a kinetic scheme containing conventional free radical polymerization reactions and equilibrium reactions of rtcp was assumed. after obtaining mass balance equations, three moment equations were defined for free and dormant radicals and dead chains. monom...
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ژورنال
عنوان ژورنال: Journal of Polymer Science Part A: Polymer Chemistry
سال: 2007
ISSN: 0887-624X
DOI: 10.1002/pola.22393