Synthesis of novel photofunctional multinuclear complexes using a coupling reaction
نویسندگان
چکیده
منابع مشابه
Synthesis of novel photofunctional multinuclear complexes using a coupling reaction.
Various photofunctional metal complexes with functional groups, i.e. bromo and vinyl groups, were integrated into hetero-multinuclear complexes using the Mizoroki-Heck reaction. The obtained trinuclear complexes absorb a wide range of visible light and have a long excited state lifetime and the photocatalytic ability to obtain CO2 reduction.
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Of all properties of metal nucleobase complexes, formation of multinuclear species appears to be an outstanding feature. After a brief introduction into well known polymeric metal nucleobase complexes, three aspects recently Studied in our laboratory will be dealt with in more detail: (i) Heteronuclear complexes derived from trans-[(amine)(2)Pt(1-MeC)(2)](2+) (1-MeC=1-methylcytosine). They form...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2015
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c5dt01717c