Synthesis of naphthoxazinone derivatives using silica-bonded S-sulfonic acid as catalyst under solvent-free conditions
نویسندگان
چکیده
منابع مشابه
Synthesis of Benzopyrano[2,3-d]pyrimidines Using Silica-Bonded N-Propyldiethylenetriamine Sulfamic Acid (SPDTSA) As Heterogeneous Solid Acid Catalyst under Solvent-Free Conditions
Silica-bonded N-propyldiethylenetriamine sulfamic acid (SPDTSA) is employed as a recyclable heterogeneous solid acid catalyst for the synthesis of benzopyrano[2,3-d]pyrimidines through one-pot condensation reaction of salicylaldehydes, malononitrile and secondary amines at room temperature under solvent-free conditions. SPDTSA showed much the same efficiency when used in con...
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An environmentally friendly, one-pot, three-component synthesis of 8,10-dimethyl-12-aryl-12H-naphtho[1′,2′:5,6]pyrano[2,3-d]pyrimidine-9,11-diones was achieved via coupling aromatic of aldehydes, β-naphthol and 6-amino-1,3-dimethyl uracil in the presence of formic acid as a catalyst under solvent-free conditions at 90 °C. This method has several advantages, such as efficiency, good yield, short...
متن کاملSilica bonded S-sulfonic acid: a recyclable catalyst for the synthesis of quinoxalines at room temperature.
The reaction of 3-mercaptopropylsilica (MPS) and chlorosulfonic acid in chloroform afforded silica bonded S-sulfonic acid (SBSSA), which was used as a catalyst for the room temperature synthesis of quinoxaline derivatives from 1,2-diamino compounds and 1,2-dicarbonyl compounds. The catalyst could be recycled and reused several times without any loss of efficiency.
متن کاملsynthesis of benzopyrano[2,3-d]pyrimidines using silica-bonded n-propyldiethylenetriamine sulfamic acid (spdtsa) as heterogeneous solid acid catalyst under solvent-free conditions
silica-bonded n-propyldiethylenetriamine sulfamic acid (spdtsa) is employed as a recyclable heterogeneous solid acid catalyst for the synthesis of benzopyrano[2,3-d]pyrimidines through one-pot condensation reaction of salicylaldehydes, malononitrile and secondary amines at room temperature under solvent-free conditions. spdtsa showed much the same efficiency when used in consecutive reaction ...
متن کاملSynthesis of 4-(trifluoromethyl) coumarins using nano sulfated-titania as solid acid catalyst under solvent-free conditions
Nano sulfated titania was tested as solid acid heterogeneous catalyst for the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives under solvent-free condition. Factorial design evidenced a positive effect of reaction temperature, amount of catalyst, and solvents. This nano-sized sulfated titania has been prepared by a sol-gel hydrothermal process. The prepared sulfated titania s...
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ژورنال
عنوان ژورنال: Journal of Chemical Sciences
سال: 2015
ISSN: 0974-3626,0973-7103
DOI: 10.1007/s12039-015-0895-x