Synthesis of a C70 Fragment Buckybowl C28H14 from a C60 Fragment Sumanene

AVICENNA ON UNIVERSALS A FRAGMENT FROM HIS LOST AL-MUJAZ

Tailoring buckybowls for fullerene recognition. A dispersion-corrected DFT study.

A series of buckybowls with different sizes and structures have been tested as potential receptors of fullerenes C60, C70 and C40. Among these bowls are corannulene (C20H10), sumanene (C21H12), pinakene (C28H14), hemifullerene (C30H12), circumtrindene (C36H12), pentaindenocorannulene (C50H20) and bowl-shaped hexabenzocoronene derivatives. An exhaustive study, taking into account different orien...

Experimental electron density of sumanene, a bowl-shaped fullerene fragment; comparison with the related corannulene hydrocarbon.

The experimental electron density of sumanene, C(21)H(12), was extracted from a high resolution X-ray data set measured at 100 K and topologically analyzed. In addition to bond topological and atomic properties, information about the density distribution between adjacent molecules, which show close C···C approaches of ~3.4 Å within the columnar π-stacks in the crystal lattice, are discussed. A ...

A LTL Fragment for GR(1)-Synthesis

The idea of automatic synthesis of reactive programs starting from temporal logic (LTL) specifications is quite old, but was commonly thought to be infeasible due to the known double exponential complexity of the problem. However, new ideas have recently renewed the interest in LTL synthesis: One major new contribution in this area is the recent work of Piterman et al. who showed how polynomial...

Detection of C60 and C70 in a young planetary nebula.

In recent decades, a number of molecules and diverse dust features have been identified by astronomical observations in various environments. Most of the dust that determines the physical and chemical characteristics of the interstellar medium is formed in the outflows of asymptotic giant branch stars and is further processed when these objects become planetary nebulae. We studied the environme...