Synthesis and crystal structure of copper(I) nitrate π-complex with 1-(4-methylphenyl)-5-allylsulfanyl-1H-tetrazole
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چکیده
منابع مشابه
Synthesis and Crystal Structure of Copper(I) Nitrate π-complex with 1-allylbenzotriazole of Equimolar Composition.
The CuNO3 • C6H4N3(C3H5) compound (I) was obtained by alternating current electrochemical synthesis, starting from an ethanol solution containing Cu(NO3)2 • 3H2O and a mixture of 1- and 2-allylbenzotriazole titrated by HNO3 to pH = 4. The C=C bond of one 1-allylbenzotriazole molecule, the nitrogen atom from another ligand moiety, and two oxygen atoms from two nitrate-anions form a trigonal-pyra...
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The reaction of CoCl(2).6H(2)O with m-BDTH(2) (1,3-benzeneditetrazol-5-yl) leads to [Co(C(8)H(6)N(8))(2)(H(2)O)(2)(CH(3)CN)(2)]Cl(2) (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network.
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1-Acetyl-3-(4-chlorophenyl)-5-(4-methylphenyl)-2-pyrazoline has been synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction. Density functional (DFT) calculations have been carried out for the title compound by using the B3LYP method at the 6-311G** basis set level. The calculated results show that the predicted geometry can reproduce well the structural pa...
متن کاملCrystal structure of 3-methyl-1-phenyl-5-(1H-pyrrol-1-yl)-1H-pyrazole-4-carbaldehyde
In the title compound, C15H13N3O, the pyrrolyl and phenyl rings make dihedral angles of 58.99 (5) and 34.95 (5)°, respectively, with the central pyrazole ring. In the crystal, weak, pairwise C-H⋯O inter-actions across centers of symmetry form dimers, which are further associated into corrugated sheets running approximately parallel to (100) via weak C-H⋯N inter-actions.
متن کاملSynthesis, Antioxidant and Antidiabetic Activity of 1-[(5-Substituted phenyl)-4,5-dihydro-1H-pyrazol-3-yl]- 5-phenyl-1H-tetrazole
N. KAUSHIK1*, N. KUMAR2, AND A. KUMAR3 School of Pharmaceutical Sciences, IFTM University, Moradabad–244102, 1School of Medical and Allied Sciences, Department of Pharmacy, Galgotias University, Greater Noida, Gautam Budh Nagar–201306, 2Oxford College of Pharmacy, UPSIDC, M-G Road, Ghaziabad–201001, 3Department of Pharmaceutical Technology, Meerut Institute of Engineering & Technology, Meerut–2...
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ژورنال
عنوان ژورنال: Visnyk of the Lviv University. Series Chemistry
سال: 2021
ISSN: 2078-5615
DOI: 10.30970/vch.6201.109