Surface-Initiated Poly(oligo(2-alkyl-2-oxazoline)methacrylate) Brushes
نویسندگان
چکیده
منابع مشابه
Polymer brushes via surface-initiated polymerizations.
Polymer brushes produced by controlled surface-initiated polymerization provide a route to surfaces coated with well-defined thin polymer films that are covalently bound to the substrate. All of the major controlled polymerization techniques have been applied to the synthesis of polymer brushes and examples of each are presented here. Many examples of brush synthesis in the literature have used...
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Surface-grafted styrene-based homopolymer and diblock copolymer brushes bearing semifluorinated alkyl side groups were synthesized by nitroxide-mediated controlled radical polymerization on planar silicon oxide surfaces. The polymer brushes were characterized by X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure (NEXAFS), and time-dependent water contact angle mea...
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Polypeptoid brushes were synthesized by surface-initiated polymerization of N-substituted glycine N-carboxyanhydrides on self-assembled amine monolayers. Using the presented grafting-from approach, polypeptoid brush thicknesses of approximately 40 nm could be obtained as compared to previously reported brush thicknesses of 4 nm. Moreover, hydrophilic, hydrophobic and amphiphilic polymer brushes...
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Electroactive conjugated polymer brushes of poly(thiophene) and poly(phenylene) have been prepared via a surface-initiated Kumada-type polycondensation reaction, yielding films with a thickness up to 42 nm.
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This paper introduces a novel and versatile method of grafting protein and cell-resistant poly(poly ethylene glycol methyl ether methacrylate) (PPEGMEMA) brushes on conducting Au surface. The process started with the electrochemical deposition and full characterization of an electro-active chain transfer agent (CTA) on the Au surface. The electrochemical behavior of the CTA was investigated by ...
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ژورنال
عنوان ژورنال: Langmuir
سال: 2018
ISSN: 0743-7463,1520-5827
DOI: 10.1021/acs.langmuir.8b01682