Surface characterization of air plasma treated poly vinylidene fluoride and poly methyl methacrylate films

Comparison of crystalline thin poly(vinylidene (70%)â•fitrifluoroethylene (30%)) copolymer films with short chain poly(vinylidene fluoride) films

We compare the photoemission and electron energy loss spectra of crystalline poly(vinylidene-fl uoride with trifl uoroethylene: 70%: 30%), P(VDF–TrFE), fi lms, fabricated by the Langmuir–Blodgett technique and annealed in vacuum, with in situ thermally evaporated fi lms of poly(vinylidene-fl uoride) (PVDF) in vacuum. Th e electronic structure and vibrational modes of the short chain PVDF fi lms...

Preparation and characterization of lithium ion conducting polymer electrolytes based on a blend of poly(vinylidene fluoride-co-hexafluoropropylene) and poly(methyl methacrylate)

Ion conducting polymer electrolytes composed of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP), poly(methyl methacrylate) (PMMA) and lithium triflate (LiTf) were prepared using the solution casting method. Structural change and complex formation in the blend electrolyte systems were confirmed from the X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and scann...

Vibrational spectroscopic characterization of form II poly(vinylidene fluoride)

The Fourier transform Raman (FT-Raman) and infrared absorption (FTIR) spectra of form II poly(vinylidene fluoride) have been recorded and analysed. A complete spectral analysis, assignments to observed bands, normal coordinate analysis and discussion of the spectra are presented. The computed spectrum is in excellent agreement with experiment. The potential energy distribution (PED) is evaluate...

Quantum Modelling of Poly(vinylidene Fluoride)

Isothermal Melt Crystallization Kinetic Behavior of Poly (vinylidene fluoride)

Isothermal melt crystallization kinetics of PVDF was investigated by differential scanning calorimetry. Thin PVDF film has been fabricated by the solvent casting technique using dimethylformamide (DMF). Then, the samples were melted and subsequently crystallized in the range of the crystallization temperature (Tc) between 138 and 145 °C. The crystallization kinetics was derived from Avrami equa...