Supramolecular Porous Organic Nanocomposites for Heterogeneous Photocatalysis of a Sulfur Mustard Simulant

Porous Organic Cages for Sulfur Hexafluoride Separation

A series of porous organic cages is examined for the selective adsorption of sulfur hexafluoride (SF6) over nitrogen. Despite lacking any metal sites, a porous cage, CC3, shows the highest SF6/N2 selectivity reported for any material at ambient temperature and pressure, which translates to real separations in a gas breakthrough column. The SF6 uptake of these materials is considerably higher th...

Study on the effective decontamination and hydrolysis of sulfur mustard agent simulant using tenorite (CuO) nanoparticles as a destructive catalyst

In the present study, tenorite (CuO) nanoparticles have been assayed for their catalytic properties. The decontamination reaction of chloro ethyl ethyl sulfide (CEES) as an surrogate of sulfur mustard simulant have been accomplished on the surface of CuO NPs with different weight ratios at ambient temperature and monitored by Gas chromatography equipped with Flame ionization detector (GC-FID) a...

Title Heterogeneous visible light photocatalysis for selective organic transformations

Selective Photooxidation of a Mustard-Gas Simulant Catalyzed by a Porphyrinic Metal-Organic Framework.

The photooxidation of a mustard-gas simulant, 2-chloroethyl ethyl sulfide (CEES), is studied using a porphyrin-based metal-organic framework (MOF) catalyst. At room temperature and neutral pH value, singlet oxygen is generated by PCN-222/MOF-545 using an inexpensive and commercially available light-emitting diode. The singlet oxygen produced by PCN-222/MOF-545 selectively oxidizes CEES to the c...

Heterogeneous visible light photocatalysis for selective organic transformations.

The future development of chemistry entails environmentally friendly and energy sustainable alternatives for organic transformations. Visible light photocatalysis can address these challenges, as reflected by recent intensive scientific endeavours to this end. This review covers state-of-the-art accomplishments in visible-light-induced selective organic transformations by heterogeneous photocat...