Supramolecular gel phase crystallization: orthogonal self-assembly under non-equilibrium conditions
نویسندگان
چکیده
منابع مشابه
Self-assembly and transformation of hybrid nano-objects and nanostructures under equilibrium and non-equilibrium conditions.
Understanding how chemically derived processes control the construction and organization of matter across extended and multiple length scales is of growing interest in many areas of materials research. Here we review present equilibrium and non-equilibrium self-assembly approaches to the synthetic construction of discrete hybrid (inorganic-organic) nano-objects and higher-level nanostructured n...
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Supramolecular polymerization has been traditionally focused on the thermodynamic equilibrium state, where one-dimensional assemblies reside at the global minimum of the Gibbs free energy. The pathway and rate to reach the equilibrium state are irrelevant, and the resulting assemblies remain unchanged over time. In the past decade, the focus has shifted to kinetically trapped (non-dissipative n...
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Through a good/poor solvent strategy, native folic acid (FA) which behaves as a super-gelator in DMSO-water system can be successfully employed to construct supramolecular gels. The system exhibited morphological evolution with the increase of FA concentration; various phases such as vesicles, fiber/vesicles, fiber/nanoparticles, nanoparticles were probed. In the self-assembly process, l-glutam...
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ژورنال
عنوان ژورنال: Chem. Soc. Rev.
سال: 2014
ISSN: 0306-0012,1460-4744
DOI: 10.1039/c3cs60224a