Supramolecular Chemistry of Multinuclear Zinc(II) Complexes in Aqueous Solution
نویسندگان
چکیده
منابع مشابه
[Supramolecular chemistry of multinuclear zinc(II) complexes in aqueous solution].
We report novel supramolecular polyhedrons formed by three-dimensional self-assembly of multinuclear zinc(II)-12-membered tetraamine (= cyclen = 1,4,7,10-tetraazacyclododecane) complexes with potentially multidentate ligands such as cyanuric acid (CA) and trithiocyanuric acid (TCA) in aqueous solution. Two new supermolecular frameworks were isolated by self-assembly of a tris (Zn(2+)-cyclen) (Z...
متن کاملSupramolecular Complexes and Supramolecular Catalysts Formed by Molecular Assembly of Multinuclear Metal Complexes in Aqueous Solutions
متن کامل
New supramolecular trigonal prisms from zinc(II)- 1,4,7,10-tetraazacyclododecane (cyclen) complexes and trithiocyanurate in aqueous solution.
The multiple bonding between multinuclear zinc(II)-1,4,7,10-tetraazacyclododecane (cyclen, a 12-membered tetraamine) complexes and multidentate ligands is an effective method for constructing supramolecular complexes having well defined and distinct structures in aqueous solution. Herein we present examples of supramolecular D(3h) prisms formed by self-assembly of linearly dimeric or trimeric z...
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A unique pH-dependent phase behavior from a copolymer micellar solution to a collapsed hydrogel with micelles ordered in a hexagonal phase was observed. Small-angle neutron scattering (SANS) was used to follow the pH-dependent structural evolution of micelles formed in a solution of a pentablock copolymer consisting of poly((diethylaminoethyl methacrylate)-b-(ethylene oxide)-b-(propylene oxide)...
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ژورنال
عنوان ژورنال: YAKUGAKU ZASSHI
سال: 2002
ISSN: 0031-6903,1347-5231
DOI: 10.1248/yakushi.122.1095