Studies on pyrazolo(3,4-d)pyrimidine derivatives. XVII. Reactions of 5-benzoyl-4,5-dihydro-6-methyl-1-phenyl-1H-pyrazolo(3,4-d)pyrimidine-4-carbonitrile (The 6-methylpyrazolopyrimidine Reissert compound).

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6,7-Dihydro-4-(4-methoxy­phen­yl)-3-methyl-6-oxo-1-phenyl-1H-pyrazolo[3,4-b]pyridine-5-carbonitrile

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In the title compound, C(24)H(21)N(3)OS, the pyrazole ring makes dihedral angles of 5.40 (7) and 6.72 (8)° with the benzo[d]thiazole ring system and the benzene ring, respectively, and a dihedral angle of 85.72 (8)° with the meth-oxy-substituted benzene ring. In the crystal structure, the mol-ecules are linked by C-H⋯π inter-actions.

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In the structure of the title compound, C(20)H(15)BrN(4)O·C(2)H(6)O, the hydrogenated pyridinone ring adopts an envelope conformation. The dihedral angle between the bromo-substituted phenyl ring and the pyrazole ring is 79.6 (1)°, and that between the non-substituted phenyl ring and the pyrazole ring is 51.2 (1)°. In the crystal structure, mol-ecules are linked via inter-molecular N-H⋯O and O-...

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6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien­yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline

In the title mol-ecule, C(29)H(22)ClN(3)S, the quinoline ring system, thio-phene ring and phenyl ring substituents are inclined at angles of 71.70 (7), 59.26 (9) and 81.61 (9)°, respectively, to the 4,5-dihydro-pyrazole ring. In the 4-phenyl-quinoline ring system, the phenyl ring makes a dihedral angle of 62.49 (7)° with mean plane of quinoline ring system. In the crystal structure, mol-ecules ...

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ژورنال

عنوان ژورنال: Chemical and Pharmaceutical Bulletin

سال: 1990

ISSN: 0009-2363,1347-5223

DOI: 10.1248/cpb.38.230