Structures of water-CO2 and methanol-CO2 cluster ions: [H2O•(CO2)n]+ and [CH3OH•(CO2)n]+ (n=1–7)
نویسندگان
چکیده
منابع مشابه
Structures of water-CO2 and methanol-CO2 cluster ions: [H2O x (CO2)n]+ and [CH3OH x (CO2)n]+ (n = 1-7).
Infrared photodissociation (IRPD) spectra of [H(2)O x (CO(2))(n)](+) and [CH(3)OH x (CO(2))(n)](+) (n=1-7) are measured in the 1100-3800 cm(-1) region. At the same time, the solvation characteristics in the clusters are investigated theoretically; the geometry optimization and the vibrational analysis are carried out for the [H(2)O x (CO(2))(n)](+) (n=1-4) and the [CH(3)OH x (CO(2))(n)](+) (n=1...
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Infrared photodissociation (IRPD) spectra of (OCS)n(+) and (OCS)n(-) (n = 2-6) cluster ions are measured in the 1000-2300 cm(-1) region; these clusters show strong CO stretching vibrations in this region. For (OCS)2 +) and (OCS)2(-), we utilize the messenger technique by attaching an Ar atom to measure their IR spectra. The IRPD spectrum of (OCS)2 (+)Ar shows two bands at 2095 and 2120 cm(-1). ...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2009
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.3116144