Structures and Energetic Properties of Two New Salts Comprising the 5,5'-Azotetrazolate Dianion
نویسندگان
چکیده
منابع مشابه
Structures and Energetic Properties of Two New Salts Comprising the 5,5'-Azotetrazolate Dianion
Two new potentially energetic salts comprising the 5,5'-azotetrazolate dianion have been prepared and structurally characterized. The new azotetrazolates are tetraphenylphosphonium-5,5'-azotetrazolate (1) and 1H-1,2,4-triazole-1-carboxamidine-5,5'azotetrazolate (2). The crystal structures of both compounds have been determined by single-crystal X-ray diffraction and their energetic properties h...
متن کاملEnergetic salts of azotetrazolate, iminobis(5-tetrazolate) and 5, 5'-bis(tetrazolate).
Energetic ionic salts of azotetrazolate (AT), iminobis(5-tetrazolate) (IBT) and 5, 5'-bis(tetrazole) (BT) were synthesized; 1-methyl-4-aminotriazolium azotetrazolate has a layered structure and exhibits a heat of formation of +4360 kJ kg(-1).
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15 صفحه اول5,5'-Azoxytetrazolates--a new nitrogen-rich dianion and its comparison to 5,5'-azotetrazolate.
A modification of the synthesis of sodium 5,5'-azotetrazolate pentahydrate, described by Thiele in 1898, yields the unknown and unexpected corresponding 5N-oxido derivative sodium 5,5'-azoxybistetrazolate pentahydrate (Na(2)zTO·5H(2)O, 1). Purification was achieved by recrystallization based on the better solubility of Na(2)zTO·5H(2)O in water. Different nitrogen-rich salts, such as the diammon...
متن کامل′ - Azoxytetrazolates – a new nitrogen - rich dianion and its comparison to 5 , 5 ′ - azotetrazolate †
A modification of the synthesis of sodium 5,5′ azotetrazolate pentahydrate, described by Thiele in 1898, yields the unknown and unexpected corresponding 5N oxido derivative sodium 5,5′ azoxybistetrazolate pentahydrate (Na2zTO·5H2O, 1). Purification was achieved by recrystallization based on the better solubility of Na2zTO·5H2O in water. Different nitrogen rich salts, such as the diammonium (3),...
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ژورنال
عنوان ژورنال: Crystals
سال: 2015
ISSN: 2073-4352
DOI: 10.3390/cryst5030405