Structural evolution and thermal stability of functionally graded NiTi nano-glass thin films alloys during crystallization
نویسندگان
چکیده
Functionally graded and composite materials are known as new materials, which exhibit higher performances provide a comprehensive application. This paper introduces bi-layer Ni-rich/NiTiCu alloy with structure comprising nano-crystal, glassy amorphous microstructure. The successive crystallization of thin films deposited at room temperature was studied by annealing 773 K for 15, 30, 60 min. Different experiments, including scanning electron microscopy (SEM), grazing incidence X-ray diffraction (GIXRD), high-resolution transmission (HRTEM), thermodynamics calculations (CALPHAD) were conducted to analyze the crystal nucleation, glassy/amorphous thermal stability against alloying elements, related interfaces studied. as-deposited fully had rounded nano-glassy structure. HRTEM images indicated no long-range periodic lattice interface between layers flat sharp. Short-time depicts non-spherical nuclei in NiTiCu layer diffuse interface. In contrast, after min annealing, NiTi mostly crystallized different structures, respectively. results confirm binary alloy. Thermodynamic diffusion studies indicate that driving force B2 ordered Cu addition along diffusivity compared Ni Ti responsible lower NiTiCu.
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ژورنال
عنوان ژورنال: Materials Characterization
سال: 2022
ISSN: ['1044-5803', '1873-4189']
DOI: https://doi.org/10.1016/j.matchar.2022.111850