Structural Change during Uniaxial Stretching of Crystalline Polymers
نویسندگان
چکیده
منابع مشابه
Stretching dynamics of semiflexible polymers.
We analyze the nonequilibrium dynamics of single inextensible semiflexible biopolymers as stretching forces are applied at the ends. Based on different (contradicting) heuristic arguments, various scaling laws have been proposed for the propagation speed of the backbone tension which is induced in response to stretching. Here, we employ a newly developed unified theory to systematically substan...
متن کاملRheology of liquid crystalline polymers
Concepts which may be used in interpreting the complex rheology of liquid crystalline polymers are reviewed. Some of them are taken from the nematodynamics of low molecular weight liquid crystals as described by the Leslie—Ericksen theory, others are intrinsic to the viscoelasticity of ordinary polymers. Tentatively, these concepts are used to construct an explanation of the band texture which ...
متن کاملSelective Modification of Film Properties through Uniaxial Stretching
The expectations placed on packaging continue to rise. It must provide enhanced product protection, greater convenience and catch the eyes of consumers while offering optimum efficiency and sustainability. Companies producing flexible packaging are responding to these challenges by developing complex, multi-layer composite films and using special raw materials. Whenever this approach reaches it...
متن کاملStretching of polymers in a turbulent environment
The interaction of polymers with small-scale velocity gradients can trigger a coil-stretch transition in the polymers. We analyze this transition within a direct numerical simulation of shear turbulence with an Oldroyd-B model for the polymer. In the coiled state the lengths of polymers are distributed algebraically with an exponent α = 2γ − 1/De, where γ is a characteristic stretching rate of ...
متن کاملStretching of semiflexible polymers with elastic bonds.
A semiflexible harmonic chain model with extensible bonds is introduced and applied to the stretching of semiflexible polymers or filaments. The semiflexible harmonic chain model allows to study effects from bending rigidity, bond extension, discrete chain structure, and finite length of a semiflexible polymer in a unified manner. The interplay between bond extension and external force can be d...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Kobunshi
سال: 1969
ISSN: 0454-1138,2185-9825
DOI: 10.1295/kobunshi.18.851