Structural Analysis of Slag Using Multinuclear Solid State NMR
نویسندگان
چکیده
منابع مشابه
Multinuclear Solid-State NMR Investigation of Hexaniobate and Hexatantalate Compounds.
This work determines the potential of solid-state NMR techniques to probe proton, alkali, and niobium environments in Lindqvist salts. Na7HNb6O19·15H2O (1), K8Nb6O19·16H2O (2), and Na8Ta6O19·24.5H2O (3) have been studied by solid-state static and magic angle spinning (MAS) NMR at high and ultrahigh magnetic field (16.4 and 19.9 T). (1)H MAS NMR was found to be a convenient and straightforward t...
متن کاملMultinuclear solid-state NMR studies of Brmsted sites in zeolites
Two NMR techniques, zH MAS NMR and echo Fourier 27AI NMR, have been applied for the first time to the investigation of Bronsted sites in dehydrated hydrogen forms ofzeolites. The “AI signal of SiOHAl sites, which was “NMR-invisible” until now, yields a quadrupole coupling constant C,,= 16 MHz for the dehydrated zeolite H-ZSM-5. The values of C,, determined from the ZH MAS NMR spectra of SiODAl ...
متن کاملA structural investigation of the alkali metal site distribution within bioactive glass using neutron diffraction and multinuclear solid state NMR.
The atomic-scale structure of Bioglass and the effect of substituting lithium for sodium within these glasses have been investigated using neutron diffraction and solid state magic angle spinning (MAS) NMR. Applying an effective isomorphic substitution difference function to the neutron diffraction data has enabled the Na-O and Li-O nearest-neighbour correlations to be isolated from the overlap...
متن کاملProtein structural analysis from solid-state NMR-derived orientational constraints.
High-resolution orientational constraints from solid-state NMR spectroscopy of uniformly aligned biological macromolecules provide a great structural analysis problem. Several approaches to this problem have been made in the past. Here a vector algebra method is developed that provides analytical solutions for the torsion angles and a concise and simple view of the structural possibilities. Num...
متن کاملucture using solid-state NMR
An overview of solid-state NMR structural studies on various silk forms and analogs conducted by the authors' research groups is presented. The well-studied silkworm and spider silks together with related silk peptides have a mixture of secondary structures including b-sheet, b-turn, helix and random coil that are difficult to analyze by X-ray diffraction and electron microscopy but convenientl...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Tetsu-to-Hagane
سال: 2003
ISSN: 0021-1575,1883-2954
DOI: 10.2355/tetsutohagane1955.89.10_1031