Straightforward One-Pot Synthesis of New 4-Phenyl-1,2,5,6-tetraazafluoranthen-3(2H)-one Derivatives: X-ray Single Crystal Structure and Hirshfeld Analyses
نویسندگان
چکیده
A straightforward one-pot route for the synthesis of a new 4-phenyl-1,2,5,6-tetraazafluoranthen-3(2H)-one is reported form direct hydrazinolysis triketo ester and hydrazine hydrate in ethanol. 4-Phenyl-1,2,5,6-tetraazafluoranthen-3(2H)-one was subjected to aza-Michael addition N-alkylation on reaction with set alkylating agents presence K2CO3. Hydrazinolysis hydrazide conversion thiosemicarbazide were successful. X-Ray single crystals analysis 1H, 13C NMR used unambiguous structure confirmation. The O…H, N…H, C…N C…C 2, C…N, C…C, C…O H…H interactions 6 are most important molecular packing based Hirshfled analysis. Moreover, short contacts both compounds revealed π–π stacking interactions.
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ژورنال
عنوان ژورنال: Crystals
سال: 2022
ISSN: ['2073-4352']
DOI: https://doi.org/10.3390/cryst12020262