Stoichiometric and Catalytic C−C and C−H Bond Formation with B(C6 F5 )3 via Cationic Intermediates
نویسندگان
چکیده
منابع مشابه
Stoichiometric and catalytic Si-N bond formation using the p-block base Al(NMe2)3.
The aluminium amide Al(NMe2)3 acts as a stoichiometric or catalytic reagent in dehydrogenic Si-N bond formation using amines and silanes. Although of limited substrate scope, this represents the first p-block metal catalytic system for N-H/Si-H dehydrocoupling. The observed catalytic rate law for the formation of aminosilane products in a model study of one of the catalytic reactions suggests a...
متن کاملConstraining the Environment of Ch+ Formation with Ch+ 3 Observations
The formation of CH+ in the interstellar medium (ISM) has long been an outstanding problem in chemical models. In order to probe the physical conditions of the ISM in which CH+ forms, we propose the use of CH3 observations. The pathway to forming CH + 3 begins with CH +, and a steady-state analysis of CH3 and the reaction intermediary CH2 results in a relationship between the CH + and CH3 abund...
متن کاملAn efficient and general route to reduced polypropionates via Zr-catalyzed asymmetric CC bond formation.
An efficient and general method for the synthesis of reduced polypropionates has been developed through the application of asymmetric carboalumination of alkenes catalyzed by dichlorobis(1-neomenthylindenyl)zirconium [(NMI)(2)ZrCl(2)]. In this investigation, attention has been focused on those reduced polypropionates that are alpha-monoheterofunctional and either omega-ethyl or omega-n-propyl. ...
متن کاملthe past hospitalization and its association with suicide attempts and ideation in patients with mdd and comparison with bmd (depressed type) group
چکیده ندارد.
simulation and experimental studies for prediction mineral scale formation in oil field during mixing of injection and formation water
abstract: mineral scaling in oil and gas production equipment is one of the most important problem that occurs while water injection and it has been recognized to be a major operational problem. the incompatibility between injected and formation waters may result in inorganic scale precipitation in the equipment and reservoir and then reduction of oil production rate and water injection rate. ...
ذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2017
ISSN: 1433-7851
DOI: 10.1002/anie.201704789