Stable carbon isotope ratio measurements with a gas density meter

New approaches for stable isotope ratio measurements

We demonstrate the first successful application of infrared laser spectrometry to the accurate, simultaneous determination of the relative H/H, O/O, and O/O isotope abundance ratios in natural water. The method uses a narrow line width color center laser to record the direct absorption spectrum of low-pressure gas-phase water samples (presently 10 μl liquid) in the 3 μm spectral region. The pre...

Gas chromatography/combustion/isotope ratio mass spectrometric analysis of the stable carbon composition of tetrols.

The stable carbon isotope compositions of tetrols, erythritol and threitol were determined by gas chromatography/combustion/isotope ratio mass spectrometry (GC/C/IRMS). Using four tetrols with various delta(13)C values derivatized by methylboronic acid, the carbon isotope analysis method achieved excellent reproducibility and high accuracy. There was no carbon isotopic fractionation during the ...

Stable Carbon Isotope Ratio Measurements of the Carboxyl Carbons in Bone Collagen

Stable carbon isotope analyses of nanogram quantities of particulate organic carbon (pollen) with laser ablation nano combustion gas chromatography/isotope ratio mass spectrometry

RATIONALE Analyses of stable carbon isotope ratios (δ13 C values) of organic and inorganic matter remains have been instrumental for much of our understanding of present and past environmental and biological processes. Until recently, the analytical window of such analyses has been limited to samples containing at least several μg of carbon. METHODS Here we present a setup combining laser abl...

Guidelines and recommended terms for expression of stable-isotope-ratio and gas-ratio measurement results.

To minimize confusion in the expression of measurement results of stable isotope and gas-ratio measurements, recommendations based on publications of the Commission on Isotopic Abundances and Atomic Weights of the International Union of Pure and Applied Chemistry (IUPAC) are presented. Whenever feasible, entries are consistent with the Système International d'Unités, the SI (known in English as...