Spectrophotometric determination of copper with zephiramine
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چکیده
منابع مشابه
Spectrophotometric Determination of Copper
The utility of Patton and Reeder’s indicator, HHSNNA, for the trace spectrophotometric and visual colorimetric determination of Cu 2+ is explored. A wine red complex of composition 1:1 is found to be formed between Cu 2+ and HHSNNA. The complex has λmax at 530 nm with ε = 25,558 L mole -1 cm -1 and is stable for more than 2 hrs. Beer’s law is obeyed between 0 to 1.5 ppm. The developed procedure...
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Spectrophotometric method for determination of cu(II) in the trace quantities was developed by using piperazine dithiocarbamate as ligand in ammonium chloride-ammonium hydroxide medium at pH -9.5. The procedure developed was applied for the estimation of cu(II) in microgram quantities in the water samples and the method developed was found to be simple and sensitive. Spectrophotometry is one of...
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A procedurefor the determination of microgramquantities of copper in biologicmaterial is described. The sample is wet-ashed with a nitric acid-perchloric acid mixture. The copper is extracted from an alkaline solutionof the ash with a solutionof diphenylcarbazide in benzene. Absorbanceof the red complex is read at 540 m1&. The copperin as little as0.5 ml. of serum can be determined and the meth...
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A method for the simultaneous spectrophotometric determination of cadmium, copper and zinc based on the formation of their complexes with 1,5-bis(di-2-pyridylmethylene)thiocarbonohydrazide is proposed. The absorption curves of these complexes overlap severely in the scanning range 380-480 nm. The analyte concentrations are calculated by a least squares fit of the pure spectra to the mixture spe...
متن کاملSpectrophotometric Determination of Copper(II) Using Diamine-Dioxime Derivative
A simple, rapid and sensitive spectrophotometric method is herewith proposed for the determination of copper(II) by using diamine-dioxime ligand, meso-3,6,6,9-tetramethyl-4,8-diazaundecane-2,10-dione dioxime or meso-HexaMethyl Propylene Amine Oxime (meso-HMPAO). This method is based on the formation of a stable 1 : 1 red-pink complex between copper(II) and meso-HMPAO in aqueous solution. Absorp...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1966
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.15.125