Special articles on zeolite chemistry and technology. Crystallization of zeolite ZSM-5 from cristobalite rock.
نویسندگان
چکیده
منابع مشابه
Zeolite ZSM-5 Membranes Grown on Porous a-A1203
Zeolites have found widespread applications as catalysts and separation media. A L present, all technologies exploiting these materials use the zeolite in powder composite form. The desire to translate the molecular sieving properties of zeolite powder composites into a membrane configuration has long been recognized. To prepare such a membrane, the crystals must grow in an interlockng fashion ...
متن کاملXylenes Reactions and Diffusions in ZSM-5 Zeolite based Catalyst
Xylenes transformations have been investigated over ZSM-5 zeolite in a riser simulator that mimics closely the operation of commercial fluidized-bed reactors. P-xylene was found to be more reactive than the other isomers followed by o-xylene and m-xylene was found to be least reactive. The order of reactivity is consistent with the order of diffusivity. At low temperature (400°C), isomerization...
متن کاملHigh-pressure cation-exchange treatment of a ZSM-5 zeolite
ZSM-5 zeolite is an aluminosilicate that usually has a high silica-to-alumina ratio. It contains two sets of nanopores. One set of nanopores is straight, with the cross-sectional size of 5.3 5.6 Å; the other set is Sshaped, with the cross-sectional size of 5.2 5.5 Å. An A1 atom at the center of an AlO4 tetrahedron connects to adjacent SiO4 tetrahedron by sharing an O atom and thus generates a n...
متن کاملOptical properties of chalcogen-loaded zeolite (ZSM-5)
Sulfur, selenium, and tellurium were loaded into sub-mm size ZSM-5 single crystals and the optical properties have been comparatively studied. S and Te show similar features, while Se is unique. S and Te have optical absorption edges at wavelengths of ~400 nm with transmission dips at ~450 nm, while Se has the edge at ~550 nm. The three materials provide photoluminescence at visible wavelengths...
متن کاملZSM-5 Zeolite As Host Material for Semiconductor Nanoparticles
This work describes the optical and structure properties of nickel sulfide and cobalt sulfide nanoparticles in ZSM-5 zeolite. The samples were obtained by sulfidation of the Ni2+ and Co2+ ion-exchange ZSM-5 zeolites in a Na2S solution at room temperature. The optical properties of the samples were studied by UV-visible spectroscopy. Their crystalline structure and morphology were studied by X-r...
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1989
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1989.352