Solvent Chemistry

Interfacial Chemistry in Solvent

Some Aspects of Chemistry in Strongly Acidic Solvent Media

An account is given of some recent developments in the chemistry of solutions in highly associated strong protonic acid solvents, including sulphuric acid and oleums, fluorosuiphuric acid and hydrogen fluoride. Topics discussed include solvent—solute interactions, super-acid systems, Hammett acidity functions and polyatomic cations of the elements of Groups VI and VII.

Aspects of Solvent Chemistry for Calcium Hydroxide Medicaments

Calcium hydroxide pastes have been used in endodontics since 1947. Most current calcium hydroxide endodontic pastes use water as the vehicle, which limits the dissolution of calcium hydroxide that can be achieved and, thereby, the maximum pH that can be achieved within the root canal system. Using polyethylene glycol as a solvent, rather than water, can achieve an increase in hydroxyl ions rele...

Solvent extraction: the coordination chemistry behind extractive metallurgy.

The modes of action of the commercial solvent extractants used in extractive hydrometallurgy are classified according to whether the recovery process involves the transport of metal cations, M(n+), metalate anions, MXx(n-), or metal salts, MXx into a water-immiscible solvent. Well-established principles of coordination chemistry provide an explanation for the remarkable strengths and selectivit...

Solvent Chemistry in the Electronic Cigarette Reaction Vessel

Knowledge of the mechanism of formation, levels and toxicological profiles of the chemical products in the aerosols (i.e., vapor plus particulate phases) of e-cigarettes is needed in order to better inform basic research as well as the general public, regulators, and industry. To date, studies of e-cigarette emissions have mainly focused on chromatographic techniques for quantifying and compari...