Sodium tetrachloroaurate(III) dihydrate-catalyzed efficient synthesis of 1,5-benzodiazepine and quinoxaline derivatives
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چکیده
منابع مشابه
Vitamin C as a green and efficient catalyst in synthesis of quinoxaline derivatives at room temperature
A simple, highly efficient and green procedure for the condensation of o-phenylenediamines with 1, 2-dicarbonyl compounds in the presence of vitamin C, as an inexpensive organocatalyst, is described. Using this method, variety of quinoxaline derivatives with different electron releasing and electron withdrawing substituents, are produced in high to excellent yields at room temperature in ethano...
متن کاملEfficient TCT-catalyzed synthesis of 1,5-benzodiazepine derivatives under mild conditions.
2,4,6-Trichloro-1,3,5-triazine (TCT) efficiently catalyzed the condensation reactions between 1,2-diamines and various enolizable ketones to afford 1,5-benzodiazepines in good to excellent yields. Simple and mild reaction conditions, the use of a cheap catalyst and easy workup and isolation are notable features of this method.
متن کاملVitamin C as a green and efficient catalyst in synthesis of quinoxaline derivatives at room temperature
A simple, highly efficient and green procedure for the condensation of o-phenylenediamines with 1, 2-dicarbonyl compounds in the presence of vitamin C, as an inexpensive organocatalyst, is described. Using this method, variety of quinoxaline derivatives with different electron releasing and electron withdrawing substituents, are produced in high to excellent yields at room temperature in ethano...
متن کاملSynthesis of tetrazolo [1,5-a]quinoxaline derivatives
Displacement reaction of 2,3-dichloroquinoxaline with secondary amines in boiling ethanol afforded it`s mono aminoquinoxaline derivatives. Further reaction of the latter compounds with sodium azide in warm dimethylsulfoxide achieved a group of 4-amino tetrazolo[1,5-a]quinoxaline derivatives. 1HNMR spectra of these compounds are discussed.
متن کاملA Fast and Efficient Method for the Synthesis of 1,5-Benzodiazepine Derivatives Under Solvent-Free Conditions
Silica sulfuric acid is found to catalyze efficiently the condensation of o-phenylenediamines with various linear and cyclic ketones to afford the corresponding 1,5-benzodiazepines in quantitative yields under solvent-free conditions at room temperature
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ژورنال
عنوان ژورنال: Journal of Zhejiang University SCIENCE B
سال: 2010
ISSN: 1673-1581,1862-1783
DOI: 10.1631/jzus.b0900288