Smoluchowski Reaction Kinetics for Reactions of Any Order
نویسندگان
چکیده
منابع مشابه
Smoluchowski Reaction Kinetics for Reactions of Any Order
In 1917, Marian von Smoluchowski presented a simple mathematical description of diffusioncontrolled reactions on the scale of individual molecules. His model postulated that a reaction would occur when two reactants were sufficiently close and, more specifically, presented a succinct relationship between the relative proximity of two reactants at the moment of reaction and the macroscopic react...
متن کاملSoybean Oil Transesterification Reactions in the Presence of Mussel Shell: Pseudo-First Order Kinetics
Calcium oxide is one of the appropriate catalysts for biodiesel production. In this study, cheap and compatible with environment catalyst has been used. Mussel shell of Persian Gulf coast is one of the sources of calcium carbonate that is converted to calcium oxide at calcination temperature up to 950°C. Transesterification reaction was carried out at optimum condition of our previous study...
متن کاملInterfacial reactions: mixed order kinetics and segregation effects
We study A-B reaction kinetics at a fixed interface separating A and B bulks. Initially, the number of reactions R(t) approximately tn(infinity)(A)n(infinity)(B) is second order in the far-field densities n(infinity)(A), n(infinity)(B). First order kinetics, governed by diffusion from the dilute bulk, onset at long times: R(t) approximately x(t)n(infinity)(A), where x(t) approximately t(1/z) is...
متن کاملReaction rates for mesoscopic reaction-diffusion kinetics.
The mesoscopic reaction-diffusion master equation (RDME) is a popular modeling framework frequently applied to stochastic reaction-diffusion kinetics in systems biology. The RDME is derived from assumptions about the underlying physical properties of the system, and it may produce unphysical results for models where those assumptions fail. In that case, other more comprehensive models are bette...
متن کاملAb Initio Studies of ClOx Reactions: I. Kinetics and Mechanism for the OH + ClO Reaction
The reaction of OH with ClO has been investigated by ab initio molecular orbital and variational transition state theory calculations. Both singlet and triplet potential energy surfaces predicted by the G2M method are presented. The reaction was shown to take place primarily over the singlet surface by two main channels producing HO2 + Cl and HCl + O2 (∆ ), with the former being dominant. The p...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: SIAM Journal on Applied Mathematics
سال: 2016
ISSN: 0036-1399,1095-712X
DOI: 10.1137/15m1030509