Small‐Scale Big Science: From Nano‐ to Atomically Dispersed Catalytic Materials

The emergence of nanomaterials (NMs) has made everyone more aware the close relationship between size and performance materials. Especially, catalytic properties materials may change dramatically when macroscopic matter goes from bulk to nanometer atomic level. It is very firmly believed that “Small determines macroproperties, contains big science.” Therefore, as chemists hope, it essential rationally tune characterize deeply understand small structures. Herein, recent progress in both multi‐scale nanoscale, sub‐nano, clusters scale for various reactions focused. Specifically, reaction on microstructures science are comprehensively summarized discussed. This review systematically spans dimensions reveal performances at different scales with a unique effect. crucial understanding composition exploring their activity. Current opportunities, future challenges, outlooks application multiscale (NMs, cluster, atomically dispersed materials) catalysis, energy environmental protection, etc. outlined.