Silico-Aluminophosphate and Alkali-Aluminosilicate Geopolymers: A Comparative Review
نویسندگان
چکیده
منابع مشابه
Microstructural Characteristics of Geopolymers Based on Alkali-Activated Fly Ash
Aluminosilicate geopolymers with a high silica molar ratio have been prepared by mixing Croatian coal-ash (ASTM Class F) and sodium silicate solution (water glass, technical grade). The samples were cured at 85 °C for 8 h and 24 h in different experimental conditions. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM/EDS) have been use...
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A new open-framework aluminophosphate Na6[(AlPO4)8(OH)6]·8H2O (JU103) has been synthesized by utilization of the organotemplate-free synthetic route in alkali metal-containing system. The as-prepared JU103 possesses two-dimensional intersecting 8-ring channels. Sodium ions and water molecules in the channels facilitates JU103 excellent proton conductivity up to 3.59 × 10(-3) S cm(-1) (293 K, 98...
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Concurrently to research conducted on ordinary Portland cement (PC), new types of binders were developed during the last decades. These are formed by alkali-activation of metakaolin or ground-granulated blast furnace slag (GGBFS) and are named, respectively, geopolymers (GP) or alkali-activated slag (AAS). Four different cementitious materials were synthesised: PC, AAS, GP, and a mix GP-AAS and...
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The interplay between the solubility, structure and chemical composition of calcium (alkali) aluminosilicate hydrate (C-(N,K-)A-S-H) equilibrated at 50 °C is investigated in this paper. The tobermorite-like C-(N,K-)A-S-H products are more crystalline in the presence of alkalis, and generally have larger basal spacings at lower Ca/Si ratios. Both Na and K are incorporated into the interlayer spa...
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The present study investigates the retention mechanisms of cesium and strontium for alkali-activated cements. Retention mechanisms such as adsorption and precipitation were examined in light of chemical interactions. Batch adsorption experiments and multi-technical characterizations by using X-ray diffraction, zeta potential measurements, and the N₂ gas adsorption/desorption methods were conduc...
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ژورنال
عنوان ژورنال: Frontiers in Materials
سال: 2019
ISSN: 2296-8016
DOI: 10.3389/fmats.2019.00106