Signatures ofn→π*interactions in proteins

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Signatures of n!p* interactions in proteins

The folding of proteins is directed by a variety of interactions, including hydrogen bonding, electrostatics, van der Waals’ interactions, and the hydrophobic effect. We have argued previously that an n!p* interaction between carbonyl groups be added to this list. In an n!p* interaction, the lone pair (n) of one carbonyl oxygen overlaps with the p* antibonding orbital of another carbonyl group....

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Signatures of n→π* interactions in proteins.

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ژورنال

عنوان ژورنال: Protein Science

سال: 2014

ISSN: 0961-8368

DOI: 10.1002/pro.2413