Sequential determination of chromium(VI) and chromium(III) by potentiometric flow-injection method.
نویسندگان
چکیده
منابع مشابه
Sequential determination of free and total cyanide by flow injection
This study presents a flow injection system for the sequential determination of free (CN(-)) and total (CN(-)+ HCN) cyanide using a potentiometric method which employs two different processes for the determination of these two chemical species. The first process is based on direct detection of CN(-) using an ion-selective electrode for cyanide. In the second process, the sample is mixed with ac...
متن کاملSequential determination of iron and titanium by flow-injection analysis.
A flow-injection method has been developed for the sequential spectrophotometric determination of iron and titanium using 3,4 dihydroxybenzoic acid as chromogenic reagent. The system involves the sequential measurement of the absorbances of the complexes at 380 and 570 nm. The system is designed using a simultaneous injection of sample and reagent into separate carrier streams. The proposed met...
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An easily automatable sequential flow-injection-pervaporation method is proposed for the photometric determination of methanol and iron in vinegar. The method is based on separation of the methanol from the sample matrix by pervaporation followed by its oxidation to formaldehyde with permanganate, decolouration of the latter with S(2)O(5)(2-), and subsequent reaction of formaldehyde with p-rosa...
متن کاملDetermination of chloride in admixtures and aggregates for cement by a simple flow injection potentiometric system.
A simple flow injection system using three 3-way solenoid valves as an electric control injection valve and with a simple home-made chloride ion selective electrode based on Ag/AgCl wire as a sensor for determination of water soluble chloride in admixtures and aggregates for cement has been developed. A liquid sample or an extract was injected into a water carrier stream which was then merged w...
متن کاملDetermination of dipyrone in pharmaceutical products by flow injection analysis with potentiometric detection.
This work describes an FIA potentiometric procedure for the quantification of dipyrone in pharmaceutical products. For the detector, a tubular electrode comprising a polymeric membrane containing tetraoctylammonium as an electroactive material (5% w/w), dibutylphtalate as a mediator solvent (65% w/w) and PVC (30% w/w) directly applied above a graphite conductor support was used. This unit was i...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 2000
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.49.59