Scaled particle theory of gas solubility — inclusion of the temperature dependent hard sphere term
نویسندگان
چکیده
منابع مشابه
Scaled particle theory for hard sphere pairs. I. Mathematical structure.
We develop an extension of the original Reiss-Frisch-Lebowitz scaled particle theory that can serve as a predictive method for the hard sphere pair correlation function g(r). The reversible cavity creation work is analyzed both for a single spherical cavity of arbitrary size, as well as for a pair of identical such spherical cavities with variable center-to-center separation. These quantities l...
متن کاملScaled particle theory for hard sphere pairs. II. Numerical analysis.
We use the extension of scaled particle theory presented in the accompanying paper [F. H. Stillinger et al., J. Chem. Phys. 125, 204504 (2006)] to calculate numerically the pair correlation function of the hard sphere fluid over the density range 0< or =rhosigma(3)< or =0.96. Comparison with computer simulation results reveals that the new theory is able to capture accurately the fluid's struct...
متن کاملA ug 2 00 6 Scaled Particle Theory for Hard Sphere Pairs . II . Numerical Analysis
Abstract We use the extension of scaled particle theory (ESPT) presented in the accompanying paper [Stillinger et al. J. Chem. Phys. xxx, xxx (2007)] to calculate numerically pair correlation function of the hard sphere fluid over the density range 0 ≤ ρσ ≤ 0.96. Comparison with computer simulation results reveals that the new theory is able to capture accurately the fluid’s structure across th...
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از محوری ترین اثراتی که یک فیلم سینمایی ایجاد می کند دیالوگ هایی است که هنرپیش گان فیلم میگویند. به زعم یک فیلم ساز, یک شیوه متأثر نمودن مخاطب از اثر منظوره نیروی گفتارهای گوینده, مثل نیروی عاطفی, ترس آور, غم انگیز, هیجان انگیز و غیره, است. این مطالعه به بررسی این مسأله مبادرت کرده است که آیا نیروی فراگفتاری هنرپیش گان به مثابه ی اعمال گفتاری در پنج فیلم هالیوودی در نسخه های دوبله شده باز تولید...
15 صفحه اولCollisional statistics of the hard-sphere gas.
We investigate the probability distribution functions of the free flight time and of the number of collisions in a hard-sphere gas at equilibrium. At variance with naive expectation, the latter quantity does not follow Poissonian statistics, even in the dilute limit, which is the focus of the present analysis. The corresponding deviations are addressed both numerically and analytically. In writ...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1982
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v82-263