Reversible reduction drives anion ejection and C60 binding within an FeII4L6 cage
نویسندگان
چکیده
منابع مشابه
Fullerene C60 as an endohedral molecule within an inorganic supramolecule.
The synthesis and properties of large spherical molecules and giant clusters is a fascinating field in contemporary chemistry, unifying all areas of organic/supramolecular, inorganic, and coordination chemistry as well as organometallic chemistry. Recent developments of low-valent group 13 metalloid clusters,1 chalcogeno-bridged copper, and silver clusters2 as well as giant polyoxomolybdates3 r...
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From specific heat measurements in high quality H2@C60 samples performed over a broad temperature range, we obtain the smallest yet observed splitting of rotational energy sublevels of encapsulated single H2 molecules, 0.1-0.2 meV, in the nearly spherical potential well provided by highly isotropic C60 cages. Additionally, we find evidence of the quantized oscillation state of isolated H2 in th...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2020
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c9sc05728e