Renner-Teller effects inHCO+dissociative recombination
نویسندگان
چکیده
منابع مشابه
C6H and C6D: electronic spectra and Renner-Teller analysis.
Rotationally resolved spectra of the B(2)Π - X(2)Π 0(0)(0) electronic origin bands and 11(1)(1) μ(2)Σ-μ(2)Σ vibronic hot band transitions of both C(6)H and C(6)D have been recorded in direct absorption by cavity ring-down spectroscopy through a supersonically expanding planar plasma. For both origin and hot bands accurate spectroscopic parameters are derived from a precise rotational analysis. ...
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Experimental rate coefficients for the removal of NH a 1 and ND a 1 in collisions with H and D atoms are presented; all four isotope combinations are considered: NH+H, NH+D, ND+H, and ND+D. The experiments were performed in a quasistatic laser-flash photolysis/laser-induced fluorescence system at low pressures. NH a 1 and ND a 1 were generated by photolysis of HN3 and DN3, respectively. The tot...
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In this Communication we present the first theoretical/numerical treatment of nonadiabatic coupling terms (NACT) that originate from the Renner-Teller (RT) model, namely, those that follow from the splitting of an electronic level of a linear molecule when it becomes bent. These two newly formed states are characterized by different symmetries and are designated as A and B. Our main findings: (...
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ژورنال
عنوان ژورنال: Physical Review A
سال: 2006
ISSN: 1050-2947,1094-1622
DOI: 10.1103/physreva.74.032707