Reductive deprotection of silyl groups with Wilkinson’s catalyst/catechol borane

Reductive Groups

Reductive dechlorination of BCl3 for efficient ammonia borane regeneration.

This paper reports a complete ammonia borane (AB) regeneration process in which Bu3SnH was utilized as a reductant for the reductive dechlorination of BCl3, and Et2PhN was selected as a 'helper ligand' to generate Et2PhN·BH3, which gives rise to a high yield of AB by a base-exchange reaction at ambient temperature.

Representations of Reductive Groups

This course consists of two parts. In the first we will study representations of reductive groups over local non-archimedian fields [ such as Qp and Fq((s))]. In this part I’ll closely follow the notes of the course of J.Bernstein. Moreover I’ll often copy big chanks from these notes. In the second the representations of reductive groups over 2-dimensional local fields [ such as Qp((s))]. In th...

The chemoselective and efficient deprotection of silyl ethers using trimethylsilyl bromide.

An efficient and chemoselective cleavage of silyl ethers (primary, secondary and aromatic) by using catalytic quantities of trimethylsilyl bromide (TMSBr) in methanol is reported. A wide range of alkyl silyl ethers such as TBS, TIPS, and TBDPS can be chemoselectively cleaved in high yield in the presence of aryl silyl ethers. The deprotection of silyl esters was also achieved employing catalyti...

Pseudo-reductive Groups

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